Periodic Table
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Chemistry Regents June 2006 - Question 31 |
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Correct answer: (4) Their metallic properties increase and their atomic radii increase.
Why?:
Atomic radius increase as we go down from top to bottom in the periodic table. This is due to the increase in the number of electrons in an atom. The additional electrons are numerous enough to occupy a new energy level, which determines the size of an atom. Atomic radius decreases as we go across from left to right. Although the number of electrons also increases in the elements from left to right of the periodic table, they occupy the same outermost energy level. No new energy level is created to accommodate them. This means the there are many electrons surrounding the positive nucleus. With this, the attraction between the negative electrons and the positive nucleus gets intensified. This intensified attraction gets the electrons closer to the nucleus. Thus, it makes the atom get smaller in size.
Metallic property decreases as we go from left to right of the periodic table and increases as we go down from top to bottom. This property has something to do with how easily valence electrons can be cleaved off the atom. Elements having 1 to 3 valence electrons are considered metallic because these elements prefer to give up their few valence electrons rather than seek for more to have a complete set of eight valence electrons to be stable. Those having 5 to 7 valence electrons prefer to be added with 1 to 3 more electrons than to give up their valence electrons to have a complete set of 8 valence electrons. These elements are nonmetallic. Fewer valence electrons can be found on the left side of the periodic table. Those with greater number of valence electrons are found on the left side of the periodic table.
Answering this question:
If you cannot analyze how the trend goes or how to come up with a good rationale, it is beneficial to always remember that fluorine is the smallest element and francium is the most metallic element. Locate their positions in the periodic table. It is easy to remember them because they are located in the two corners of the periodic table. Fluorine is the 1st element under group 17. Knowing this, we would have an idea that the elements below fluorine are bigger.
With francium's location, it can be easily determined that the elements above it are less metallic. You do the same analogy with the elements under group 15.
So this leaves us with (4) as the correct answer.
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Last Updated on Wednesday, 23 December 2009 15:49 |
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Chemistry Regents June 2006 - Question 13 |
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Correct answer: (2) fluorine
Why?:
The ability of an atom to attract electrons towards itself is called electronegativity. Electronegativity decreases with atomic size. As we go from left to right in the periodic table, electronegativity increases. And as we go from bottom to top of the periodic table, electronegativity also decreases. Fluorine is located on the top right corner of the periodic table. It is in fact the most electronegative element in the periodic table. Therefore, it has a strong pull of the electrons towards itself.
Answering this question:
On the left side of the periodic table are nonmetals. Considering the periodic trend of the electronegativity of the elements, the nonmetals are more electronegative compared to metals. Metals are located on the left side of the periodic table. In this question, (1) and (3) can be eliminated immediately because they are metals. They are located on the left side of the periodic table. The competition is just between oxygen and fluorine. Both of them are strongly electronegative. But comparing the two, fluorine has a smaller size. This means that the electrons in a bond between fluorine and another atom are much closer to the nucleus of fluorine than those in an oxygen atom. The closer the electrons to the nucleus, the more easily the electrons would be pulled towards the nucleus. Due to the smaller size of fluorine, it is more electronegative than oxygen.
So this leaves us with (2) as the correct answer.
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Last Updated on Wednesday, 23 December 2009 14:50 |
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Chemistry Regents June 2006 - Question 02 |
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Correct Answer: (4) Sr
Why?:
The elements in the periodic table are arranged in such a way that elements having similar properties or characteristics will be belonging to the same group or column. Calcium belongs to group IIA of the periodic table. This is also known as group 2. The elements under the group IIA have 2 valence electrons and they are capable of donating those 2 valence electrons, hence, the oxidation state of +2. From among the choices, Sr is the only element that also belongs to group IIA.
Answering this question:
Sodium (Na) and potassium (K), both belong to group IA of the periodic table. They are metals having the oxidation state of +1. They both have similar properties. Cobalt (Co) is a transition metal found in the lower inner box of the periodic table. It has variable oxidation state and it definitely does not belong to group IIA as where calcium belongs. Strontium (Sr) can be found under the group IIA and since it has the same group as calcium, then they have similar properties.
So the correct answer is (4).
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Last Updated on Wednesday, 23 December 2009 14:29 |
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